國二下理化
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內容架構
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化學反應
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定律
1.原子不滅:質量守恆、原子數守恆(反應前後)
2.比例固定:質量比固定、分子數比固定
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計量單位
1.原子質量單位:原子量(amu)≒質量數
*原子量非SI單位,是以碳12作為基準的比較量
*1amu的大小約為一個質子或中子的質量
2.原子數量單位:莫耳數(mol)=6x1023
單位換算
➜ 一莫耳的質子或中子≒1公克
➜公克(g)=原子量(amu)*莫耳數(mol≒6x1023)
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:BULB:常見元素的原子量
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反應式
1.係數比=分子數比=莫耳數比
(氣體反應時等於體積比)
2.總原子量比=質量比
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氧化還原
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氧化還原
定義:氧原子的得失的化學反應。
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氧化還原中,氧化與還原同時進行
進行氧化反應的物質,稱為還原劑(還原別人)
進行還原反應的物質,稱為氧化劑(氧化別人)
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氧化還原的應用
高爐煉鐵
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高爐煉鐵-製備反應
高爐煉鐵-泥沙作用
- 氧化鈣與礦石中的泥沙形成熔渣(可在表面防止鐵被氧化)
生鐵、熟鐵、鋼的比較
日常生活
- 蠟燭燃燒(蠟燭氧化;氧氣還原)
- 鐵生鏽 (鐵氧化;氧氣還原)
- 高爐煉鐵 (煤焦氧化;鐵礦還原)
- 呼吸作用 (葡萄糖氧化;氧氣還原)
- 次氯酸鈉消毒水作用 (細菌氧化;消毒水還原)
- 抗氧化劑作用 (抗氧化劑氧化;其他物質還原)
- 漂白劑作用 (色素經氧化還原後變色)
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其他
燃燒為劇烈的氧化還原,不同元素燃燒有不同焰色。
- 金屬氧化物溶於水為鹼性;非金屬氧化物溶於水為酸性
- 銅不會燃燒,氧化之後會產生黑色的氧化銅
有些金屬氧化物質地緻密,防止內部持續氧化(鋁、鈦、鋅)
有些金屬活性大到存放在石油(鹼金族);或地殼(鹼土族)
常見元素活性大小比較如下:
- 活性:鉀>鈉>鈣>鎂>鋁>碳>鋅>鐵>鉛>銅>汞>銀>鉑>金
元素活性強,容易氧化,其氧化物較安定;元素活性弱,不易氧化,其氧化物較不安定
註
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酸、鹼、鹽
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電解質:化合物、溶於水、會解離
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電離說:由瑞典化學家阿瑞尼士提出
- 電解質在水中會解離出帶電的離子or根離子
- 電解質水溶液是電中性
- 通電時,負離子往正極;正離子往負極
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補充:鋅銅電池
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電解-化學反應(惰性電極)
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電解-化學反應(電極參與反應)
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電化學反應順序
- 還原反應(得到電子): Ag+>Cu2+>H+>Na+>K+
- 氧化反應(失去電子): 正極金屬(Ag前)>Cl->OH->含氧酸根離子
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酸與鹼
酸與鹼的通性
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常見的酸
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食鹽+硫酸→生成鹽酸
鹽酸+含氯漂白水→生成氯氣
稀硝酸+銅→生成NO
濃硝酸+銅→生成NO2
硝酸混和鹽酸(1:3)=王水
工業排放硫、氮的氧化物,在大氣中形成硫酸、硝酸(酸雨)
常見的鹼

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酸鹼濃度
1.體積莫耳濃度(M):每公升的溶液含有溶質的莫耳數
(註: 溶質量=溶液量x濃度)

2.pH值:若氫離子體積莫耳濃度=10-KM→pH值=K
(25oC時,氫離子的體積莫耳濃度[H+] x 氫氧根的體積莫耳濃度[OH-]=10-14)
- 中性水溶液,[H+]=[OH-]=10-7,此時pH值=7
- 酸性水溶液,[H+]>10-7;[OH-]<10-7,此時pH值<7
- 鹼性水溶液,[H+]<10-7;[OH-]>10-7,此時pH值>7


加水稀釋酸和鹼:逐漸趨近中性

酸鹼示劑

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酸鹼中和
酸鹼中和反應:酸性溶液和鹼性溶液混和時的化學反應(放熱)

酸鹼滴定

pH值變化曲線

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常見的鹽類
(酸鹼中和、鹽類加酸等方法可製得鹽類)

註


反應速率
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意義
反應速率=化學反應的快慢= 產量/時間 或 耗量/時間
(若產量固定,時間的倒數可表示反應速率)
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影響因素: 濃度、表面積、溫度(增加碰撞)、活性、催化劑
碰撞學說:化學反應中粒子必須互相碰撞,使原子重新排列
催化劑作用:增加反應途徑、參與反應後釋出(質量不變)

EX:二氧化錳分解

反應速率實驗
A.顆粒越小(接觸面積越大),反應速率越快
大理石與鹽酸反應,產生二氧化碳
CaCO3 + 2HCl → CaCl2 + CO2 + H2O

B.溫度越高,反應速率越快
硫代硫酸鈉與鹽酸反應,產生黃色的硫沉澱
Na2S2O3 + 2HCl → 2NaCl + SO2 + S + H2O
(S2O32- + 2H+ → SO2 + S + H2O)
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可逆反應平衡方向:判斷正逆反應的有利因素(反應物、環境)
正反應有利因素增加 → 反應往正反應
正反應有利因素減少 → 反應往逆反應
逆反應有利因素增加 → 反應往逆反應
逆反應有利因素減少 → 反應往正反應

可逆反應速率

補充

有機化合物
整理
力與壓力
力與壓力
現象 |
公式 |
應用 |
力會改變形狀(或運動狀態) |
彈簧長度變化∝力的大小 |
 |
摩擦力會防止物體滑動 |
正向力∝最大靜摩擦力(止滑) |
 |
力作用在平面上造成壓力 |
壓力=力/面積 |
 |
物體泡在液體會受到液體壓力 |
液體壓力=液體密度x深度 |
 |
物體泡在液體會受到向上的浮力 |
浮力=沉入體積x液體密度 |
 |
浮力
浮力的定義
液體向上支撐物體的力(物體泡到液體)

基本計算:力平衡的方式計算
1.浮體:浮力=重力
2.潛體:浮力=重力
3.沉體:浮力=重力-支撐力
<註>物體質量=體積x密度(國二上)
<註>物體密度大於液體,則下沉;密度小於液體,則上浮(國二上)
浮力的公式
浮力受兩個因素影響:物體沉入體積、液體密度
物體沉入體積越多,浮力越大 EX:浮板飄在水上vs浮板壓進水中
液體本身密度越大,浮力越強 EX:浮板壓進水中vs浮板壓進鹽海

浮力公式:浮力=沉入體積x液體密度
浮力=沉入體積x液體密度
<註>沉入體積=排開液體體積(國二上)
浮力=排開液體體積x液體密度=排開液體重量
浮力的統整與應用
統整
浮力定義:液體向上支撐物體的力(物體泡到液體) *減輕
一個主要公式:浮力=沉入體積x液體密度 *排開液體重
兩個主要情況:
浮體:浮體的物重=浮力 沉體:沉體的體積=沉入體積
應用
質量50g、體積100cm3物體浮於水(密度1g/cm3),求以下空白處之物理量
(浮力、沉入體積、物體密度)

質量20g、體積5cm3物體沉入液體(密度2g/cm3),求以下空白處之物理量
(浮力、沉入體積、物體密度)

質量100g、密度0.5g/cm3的球沉入水(1g/cm3)中,求以下空白處之物理量以及球泡在水面下的比例

浮體泡在水面下的比例=浮體密度/液體密度
沉入體積x液體密度=浮體體積x浮體密度
沉入體積/浮體體積=浮體密度/液體密度
密度2g/cm3的物體泡入水(1g/cm3)中彈簧秤顯示減輕10gw,求空白處之物理量

浮力=液體向上支撐物體的力(物體泡到液體)=物體減輕重量
密度2g/cm3的物體投入密度0.5g/cm3的液體中,液體排開了100g,求空白處之物理量

浮力=沉入體積x液體密度=排開液體體積x液體密度=排開液體重
補充:沉船時,浮力變(大/小),物體沉入體積或液體排開體積變(大/小) * 易錯

補充:比較誰的浮力大



補充:浮力=沉入體積x液體密度 浮力變化=沉入體積變化x液體密度
