## Chapter 5 & 9: Chemical Reactions, Acids, and Bases Here's a summarized outline of the PDF, incorporating bullet points, tables, and quizzes for better comprehension and memorization. **Chapter 5: Chemical Reactions** **5.1 Introduction to Chemical Reactions** * **Physical Change:** Alters the physical state of a substance without changing its composition. * **Chemical Change:** Converts one substance into another by breaking bonds in reactants and forming new bonds in products. **5.2 Balancing Chemical Equations** 1. Write the equation with correct formulas. 2. Balance the equation with coefficients one element at a time. 3. Check to make sure the smallest set of whole numbers is used. **5.3 Types of Reactions** | Type of Reaction | Description | Example | |---|---|---| | Combination | Joining of two or more reactants to form a single product | A + B → AB | | Decomposition | Conversion of a single reactant to two or more products | AB → A + B | | Single Replacement | One element replaces another element in a compound | A + BC → AC + B | | Double Replacement | Two compounds exchange "parts" to form two new compounds | AB + CD → AD + CB | **5.4 Oxidation and Reduction** * **Oxidation:** Loss of electrons from an atom. * **Reduction:** Gain of electrons by an atom. * **Redox Reaction:** Involves the transfer of electrons from one element to another. * **Oxidizing agent:** Causes another compound to be oxidized (itself gets reduced). * **Reducing agent:** Causes another compound to be reduced (itself gets oxidized). * **Examples:** * Iron rusting (4Fe + 3O2 → 2Fe2O3) * Zn + 2MnO2 → ZnO + Mn2O3 **5.5 The Mole and Avogadro's Number** * **Mole:** A quantity containing 6.02 x 10^23 items. * **Avogadro's Number:** 6.02 x 10^23. **5.6 Mass to Mole Conversions** * **Formula weight:** Sum of atomic weights of all atoms in a compound (amu). * **Molar mass:** Mass of one mole of any substance (g/mol). * Relates number of moles to grams of a substance. **5.7 Mole Calculations in Chemical Equations** * Balanced equations indicate the number of moles of each reactant and product. * **Mole ratios:** Serve as conversion factors. **5.8 Mass Calculations in Chemical Equations** * Convert moles of reactant to grams of product using mole ratios and molar mass. **5.9 Percent Yield** * **Theoretical yield:** Expected amount of product based on balanced equation. * **Actual yield:** Isolated amount of product from a reaction. * **Percent yield = (actual yield / theoretical yield) x 100%** **5.10 Limiting Reactants** * **Limiting reactant:** Completely used up in a reaction. * Determines the maximum amount of product that can be formed. **Quiz 5 (Chapter 5)** **Question 1:** What type of reaction is represented by the equation: A + BC → AC + B ? <details> <summary>Answer</summary> Single Replacement </details> **Question 2:** What is the molar mass of H2O (Hydrogen: 1 g/mol, Oxygen: 16 g/mol)? <details> <summary>Answer</summary> 18 g/mol </details> **Question 3:** What is Avogadro's number? <details> <summary>Answer</summary> 6.02 x 10^23 </details> **Question 4:** In a chemical reaction, the substance that is completely used up is called the: <details> <summary>Answer</summary> Limiting reactant </details> **Chapter 9: Acids and Bases** **9.1 Introduction to Acids and Bases** * **Arrhenius Definition:** * Acid: Contains hydrogen and forms H+ in water. * Base: Contains hydroxide and forms OH- in water. * **Brønsted-Lowry Definition:** * Acid: Proton (H+) donor. * Base: Proton (H+) acceptor. **9.2 The Reaction of a Brønsted-Lowry Acid with a Brønsted-Lowry Base** * **Conjugate base:** Formed by loss of a proton from an acid. * **Conjugate acid:** Formed by gain of a proton by a base. * **Amphoteric compound:** Can act as both an acid and a base (e.g., water). **9.3 Acid and Base Strength** * **Strong acid:** Dissociates completely in water (e.g., HCl, H2SO4). * **Weak acid:** Dissociates partially in water (e.g., H3PO4, HF). * **Strong base:** Dissociates completely in water (e.g., NaOH, KOH). * **Weak base:** Dissociates partially in water (e.g., NH3). **9.4 Dissociation of Water** * Water can act as both an acid and a base, reacting with itself. **9.5 The Ion-Product Constant for Water (Kw)** * Kw = [H3O+][OH-] = 1.0 x 10^-14 at 25°C. **9.6 The pH Scale** * pH = -log[H3O+]. * Acidic solution: pH < 7. * Basic solution: pH > 7. * Neutral solution: pH = 7. **9.7 Common Acid-Base Reactions** * **Neutralization reaction:** Acid + Base → Salt + Water. **9.8 Titration** * Used to determine the concentration of an acid or base. * **End point:** Point at which the acid is neutralized. **Quiz 9 (Chapter 9)** **Question 1:** What is the conjugate base of HCl? <details> <summary>Answer</summary> Cl- </details> **Question 2:** A solution with a pH of 9 is: <details> <summary>Answer</summary> Basic </details> **Question 3:** Which of the following is a weak acid? <details> <summary>Answer</summary> H3PO4 </details> **Question 4:** The reaction of an acid with a base to produce salt and water is called: <details> <summary>Answer</summary> Neutralization reaction </details>